发明名称 OXIDATION OF HYDROCARBONS TO ACIDS IN THE PRESENCE OF FLUORO COMPOUNDS
摘要 This invention relates to methods of oxidizing hydrocarbons, such as cyclohexane, o-xylene, m-xylene, and p-xylene, to form a respective acid, su ch as adipic acid, phthalic acid, isophthalic acid, and terephthalic acid, for example, by introducing into the reaction mixture small critical amounts of fluorocompounds. Preferable fluorocompounds are perfluoroacids, such as for example perfluoroacetic acid, perfluorobutyric acid, and perfluorooctanoic acid. By introducing the critical amounts of the fluorocompounds, the reactivity increases without sacrificing yield and/or selectivity.
申请公布号 CA2361709(A1) 申请公布日期 2000.08.10
申请号 CA20002361709 申请日期 2000.02.04
申请人 RPC INC. 发明人 DECOSTER, DAVID C.;DASSEL, MARK W.;VASSILIOU, EUSTATHIOS
分类号 C07C51/215;C07B61/00;C07C51/31;C07C55/14;(IPC1-7):C07C51/31;C07C63/15 主分类号 C07C51/215
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