Methods of (co)polymerizing vinyl and/or diene monomers and curing or crosslinking polymeric resins using a heteropoly acid peroxide promoter

摘要

A method of (co)polymerizing vinyl and/or diene monomers comprising contacting the monomers with a (co)polymeriztion composition under conditions effective to (co)polymerize the monomers, wherein the (co)polymerization composition comprises: (a) an organic peroxide component, and (b) a heteropoly acid, in an amount effective to lower the onset temperature of decomposition of the organic peroxide component with the proviso that if the heteropoly acid is phosphomolybdic acid the organic peroxide is not a peroxydicarbonate.