发明名称 |
METHOD FOR PREPARING STYRENE/ACRYLIC WATER-SOLUBLE RESIN BY CONTINUOUS BULK POLYMERIZATION |
摘要 |
PURPOSE: A method for preparing a styrene/acrylic water-soluble resin having a small molecular weight, narrow molecular weight distribution, high acidity value and low volatile matter content by using a continuous bulk polymerization is provided. CONSTITUTION: A method comprises steps of: (i) continuously throwing a monomer, an initiator and 5-15 wt. parts of a mixed solvent of dipropylene glycol methyl ether and water regarding 100 wt. parts of the monomer in a reactor controlling the temperature by using an oil jacket and a cooling coil of the inside of the oil jacket; (ii) polymerizing the step (i) at a reaction temperature of 150-220°C and a retention time of 10-20 minutes; and (iii) transferring the polymer of step (i) to a falling strand type of devolatilizer and then operating the devolatilizer at a temperature of 180-210°C and under pressure of -500¯-750 millimeter Hg to remove volatile dust from the polymer.
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申请公布号 |
KR20000040715(A) |
申请公布日期 |
2000.07.05 |
申请号 |
KR19980056434 |
申请日期 |
1998.12.19 |
申请人 |
HANWHA CHEMICAL CORPORATION |
发明人 |
JIN, YEONG SEOB;LEE, KWANG JAE;OH, SEOK HEON;SEON, JU SANG;HA, HYEON JAE |
分类号 |
C08F2/01;C08F2/02;C08F2/10;C08F2/44;C08F6/10;C08F212/08;C08F257/02;(IPC1-7):C08F2/02 |
主分类号 |
C08F2/01 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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