发明名称 |
SELECTIVE HYDRODEHALOGENATION METHOD |
摘要 |
The invention concerns a selective hydrodehalogenation method characterised in that it comprises a step which consists in contacting a substrate including a sp<3> hybridisation carbon atom bearing an electro-attracting group and at least a fluorine atom, and a halogen atom heavier than fluorine, with a reagent comprising: an aqueous phase, a base, a group VIII metal as hydrogenation catalyst, and hydrogen dissolved in the aqueous phase, at a concentration in equilibrium with a gas phase whereof the partial pressure in hydrogen is not less than 50kPa, advantageously ranging between 50kPa and 2.10<7> Pa. The invention is applicable to organic synthesis. |
申请公布号 |
WO0035834(A1) |
申请公布日期 |
2000.06.22 |
申请号 |
WO1999FR03031 |
申请日期 |
1999.12.07 |
申请人 |
RHODIA CHIMIE;JACQUOT, ROLAND;CORDIER, GEORGES |
发明人 |
JACQUOT, ROLAND;CORDIER, GEORGES |
分类号 |
C07B31/00;C07B61/00;C07C51/377;C07C53/18 |
主分类号 |
C07B31/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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