| 摘要 |
A method for desalting and dewatering a silver halide emulsion comprising removing soluble salts from the silver halide emulsion by electrodialysis, wherein the electrodialysis is carried out by passing a feed stream of the emulsion between an anion-exchange membrane and a cation-exchange membrane while a direct current voltage is applied between the anion-exchange and cation-exchange membranes so that ions are removed from the feed stream and transferred to a waste stream on the sides of the anion-exchange and cation-exchange membranes opposite to the feed stream, wherein a soluble material is added to the waste stream at a higher concentration with respect to the feed stream so as to establish a concentration gradient between the waste stream and the feed stream which drives osmotic dewatering of the feed stream during electrodialysis. It is possible to achieve simultaneous deionization and dewatering using electrodialysis within a reasonable process time by adding a soluble component to the waste stream to generate a concentration gradient whereby water is effectively transferred from the feed to the waste concentrate stream by direct osmosis as well as removal of water by ionic hydration during electrodialysis. This process has the advantage that interactions with the emulsion being deionized does not place any restriction on the soluble component that is used to establish the concentration gradient between the feed and waste streams, because the component is not added to the emulsion feed stream. In a particular embodiment, the concentration gradient is established by adding a salt to the waste electrodialysis stream. In a preferred embodiment, relatively high water content or high porosity ion-exchange membranes are used in combination with a high level of salt (or other component) in the concentrate or waste stream.
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