| 摘要 |
<p>The prodn. of high-viscosity polypropylene graft copolymers(I) comprises reacting (a) polypropylene (PP) with a melt index (MFI 230/21.19) of 0.1-5 g/10 mins. in an extruder with (b) 1-25 wt.% radically polymerisable monomer (w.r.t. PP), i.e. maleic, fumaric or itaconic anhydride, (meth)acrylic acid or esters thereof, acrylonitrile, glycidyl (meth)acrylate, styrene, alpha-methylstyrene, vinyl acetate or butyrate, vinylpyridine, vinylalkoxysilane, isopropenyl-2-iso-oxaline and/or vinylpyrrolidone, in the presence of (c) 0.05-1 wt.% conventional peroxide, and also (d) 0.1-3 wt.% polyfunctional monomer(s), i.e. diallyl adipate or maleate, pentaerythritol or trimethylolpropane triacrylate, triallyl isocyanurate, allyl acrylate, di- or tri-vinyl-benzene, p-toluylenediamine, hexamethylenetetramine, ethylene or propylene glycol, or phthalic or pyromellitic anhydride.</p> |
