发明名称 (METH)ACRYLIC ESTER AND ITS PRODUCTION
摘要 PROBLEM TO BE SOLVED: To produce a new ester useful as a raw material monomer for resins excellent in optical characteristics, heat and water resistances and adhesion by reaction a specific olefin with a specified (meth)acrylic acid. SOLUTION: This ester is represented by formula I [R1 is H or methyl; R2 is OCOOR3, OCONR4R5 or CONR6R7 (R3 to R7 are each H or a 1-10C hydrocarbon)], e.g. 5-ethoxycarbonyloxybicyclo[2.2.1]heptyl-2- or -3-acrylate. The above compound is produced by reacting a compound represented by formula II with (meth)acrylic acid represented by formula III and carrying out the reaction in the presence of a dehydrochlorinating agent, e.g. pyridine at room temperature to 200 deg.C under atmospheric pressure in a first step and conducting the reaction in the presence of an acidic catalyst such as sulfuric acid at room temperature to 200 deg.C under the atmospheric pressure in a second step at that time.
申请公布号 JP2000154169(A) 申请公布日期 2000.06.06
申请号 JP19980328668 申请日期 1998.11.18
申请人 NIPPON ZEON CO LTD 发明人 TAKEUCHI HITOMI;TAWARA SHINICHIRO;WATANABE KIYOSHI
分类号 C07C68/06;C07C69/96;C07C231/12;C07C235/40;C07C269/06;C07C271/34;C07C271/36;C07C271/38;C08F20/28;C08F20/36;(IPC1-7):C07C69/96 主分类号 C07C68/06
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