发明名称 |
Chiral diphenyldiphosphines and d-8 metal complexes thereof |
摘要 |
<p>Compounds of formula III, <CHEM> wherein R6 und R7 signify identical or different secondary phosphino; R8 is -CH2-OH, -CH2-NH2, -CH2-O-B-FU, -CH2-NH2-B-FU, or -O-B-FU; R9 has the same significance as R8 or is C1-C4-alkyl or C1-C4-alkoxy; or R8 and R9 together signify HOCH(CH2-O-)2, H2NCH-(CH2-O-)2, FU-B-OCH(CH2-O-)2 or FU-B-HNCH(CH2-O-)2; B is a bridging group; and FU is a functional group. The compounds may be bonded to inorganic or organic carriers. Their d-8 metal complexes are valuable catalysts for the enantioselective hydrogenation of prochiral organic compounds with carbon multiple bonds or carbon/hetero atom multiple bonds.</p> |
申请公布号 |
EP1002801(A1) |
申请公布日期 |
2000.05.24 |
申请号 |
EP19990122865 |
申请日期 |
1999.11.17 |
申请人 |
SOLVIAS AG |
发明人 |
PUGIN, BENOIT;STEINER, IVO;AUFDENBLATTEN, RHONY NIKLAUS;TOGNI, ANTONIO |
分类号 |
B01J31/24;C07B53/00;C07B61/00;C07C25/18;C07C33/46;C07C39/367;C07C43/225;C07C211/52;C07F9/50;C07F9/655;C07F9/6568;C07F9/6596;C07F15/00;(IPC1-7):C07F9/50;C07B31/00;B01J31/28;C08F112/08 |
主分类号 |
B01J31/24 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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