发明名称 Process for preparing free alpha -hydroxy acids from ammonium salts thereof
摘要 PCT No. PCT/JP97/00528 Sec. 371 Date Aug. 25, 1998 Sec. 102(e) Date Aug. 25, 1998 PCT Filed Feb. 25, 1997 PCT Pub. No. WO97/30962 PCT Pub. Date Aug. 28, 1997A process for preparing alpha -hydroxy acids by heating ammonium salts of alpha -hydroxy acids of general formula (I), removing the formed ammonia and water, adding water to the residue, and heating the obtained mixture, wherein R is hydrogen, C1-C6 alkyl, alkyl(C1-C6)thioalkyl (C1-C6), phenyl or the like. This process is freed from the problem of disposal of by-products such as ammonium bisulfate and makes it possible to prepare a free alpha -hydroxy acid from an ammonium salt thereof economically and in a high yield.
申请公布号 US6066763(A) 申请公布日期 2000.05.23
申请号 US19980125710 申请日期 1998.08.25
申请人 NIPPON SODA CO., LTD. 发明人 HAYAKAWA, KOICHI
分类号 C07C51/02;C07C319/20;C07C323/52;(IPC1-7):C07C381/00;C07C59/08;C07C65/01 主分类号 C07C51/02
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