摘要 |
A method is provided for the electrolytic production of aluminum metal from aluminum trichloride starting material. A molten electrolytic solution of mixed chloride-fluoride salts is formed in a reaction vessel into which the aluminum trichloride feed material is added. The fluoride component of the electrolyte reacts spontaneously with the aluminum trichloride, producing aluminum fluoride and a chloride salt. The aluminum fluoride is advantageously stored in a non-volatile state in solution in the electrolyte. The aluminum fluoride is then electrolytically reduced to yield aluminum metal and a fluoride salt.
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