发明名称 PRODUCTION OF AROMATIC-ALIPHATIC COPOLYCARBONATE
摘要 PROBLEM TO BE SOLVED: To obtain an aromatic-aliphatic copolycarbonate having excellent impact and heat resistances, a high Abbe number and a low photoelastic constant, excellent in color tone and useful as an optical material or the like by adopting a specific transesterification condition. SOLUTION: When performing the transesterification of (A) an aromatic dihydroxy compound (preferably bisphenol A) of formula I [wherein, X a single bond, a group expressed by formula II (wherein, R3 and R4 are each H, a 1-12C alkyl or phenyl) or the like; R1 and R2 are each H, a 1-10C alkyl, a cycloalkyl or the like; (m) and (n) are the number of substituents and are each 0-4] with both (B) a tricyclo(5.2.1.02.6)decanedimethanol of formula II and (C) a carbonic diester (preferably diphenyl carbonate or the like), the aldehyde content in the component B is <=0.5 mg/(1 g component B) in terms of KOH.
申请公布号 JP2000136241(A) 申请公布日期 2000.05.16
申请号 JP19980310818 申请日期 1998.10.30
申请人 MITSUBISHI GAS CHEM CO INC 发明人 NAGAI SATOSHI;KONISHI TAKASHI;SASAKI MAKOTO
分类号 C08G64/16;C08G64/30;G02B1/04;(IPC1-7):C08G64/30 主分类号 C08G64/16
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