发明名称 PRODUCTION OF ARYLOXYTITANIUM COMPLEX
摘要 PROBLEM TO BE SOLVED: To industrially obtain a high purity aryloxytitanium complex useful for a transesterification catalyst or the like in high yield by reacting a specific halogenated titanium complex with a specific alkali metal aryl oxide. SOLUTION: By reacting a halogenated titanium complex of formula I [Cp is a group having a cyclopentadiene-type anion skeleton; A is C or Si; R1-R4 are each H, a (halogen-substituted) 1-10C alkyl, a (fluorine-substituted) 1-10C alkoxy, a (fluorine-substituted) 6-20C aryloxy or the like; R5 and R6 are each H, a (fluorine-substituted) 1-10C alkyl or the like; X1 and X2 are each a halogen] with an alkali metal aryl oxide of formula II [M is an alkali metal; Ar is a (substituted) 6-20C aryl], an aryloxytianium complex of formula III [e.g. (η5-cyclopentadienyl)(2-phenoxy)methanetitaniumdiphenoxide or the like] is obtained.
申请公布号 JP2000086678(A) 申请公布日期 2000.03.28
申请号 JP19980257006 申请日期 1998.09.10
申请人 SUMITOMO CHEM CO LTD 发明人 HANAOKA SHUSUKE;ODA YOSHIAKI
分类号 C07F7/28;C08F4/64;(IPC1-7):C07F7/28 主分类号 C07F7/28
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