发明名称 |
METAL/ORGANIC POLYMER COMPOSITE STRUCTURE CONTAINING ULTRAFINE METAL PARTICLES ARRANGED IN ROW AND PROCESS FOR PRODUCING THE SAME |
摘要 |
A metal/organic polymer composite structure comprising a micro-domain structure which comprises a block copolymer made up of two or more incompatible polymer chains bonded in an end-to-end manner and in which one of the polymer phases selectively contains ultrafine metal particles arranged in rows; and a process for producing the composite structure which comprises (i) the step of dissolving metal ions and a block copolymer comprising one or more polymer chains having an affinity for the metal and, bonded thereto in an endto-end manner, one or more polymer chains having no or little affinity for the metal in a mixed solvent in which the polymer and the metal ions are soluble and which comprises a solvent having the ability to reduce the metal ions and having a boiling point of 80 to 200 ~C and a solvent having a boiling point of 10 to 80 ~C; (ii) the step of removing the low-boiling solvent at the boiling point thereof to cause the block copolymer to form a micro-domain structure; and (iii) the step of reducing the metal ions thereafter while removing the high-boiling solvent at the boiling point thereof. |
申请公布号 |
CA2307775(A1) |
申请公布日期 |
2000.03.09 |
申请号 |
CA19992307775 |
申请日期 |
1999.08.26 |
申请人 |
JAPAN SCIENCE & TECHNOLOGY CORPORATION |
发明人 |
HASHIMOTO, TAKEJI;HARADA, MASAFUMI |
分类号 |
C08J5/00;C08F293/00;C08K3/08;C08L53/00;(IPC1-7):C08L53/00;C08J3/09 |
主分类号 |
C08J5/00 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|