发明名称 |
IMPROVED METHOD FOR PRODUCING HEXAMETHYLENE DIAMINE |
摘要 |
The invention relates to a method for the catalytic hydrogenation of adipodinitrile to hexamethylene diamine at a high temperature and at high pressure in the presence of catalysts based on elementary iron as the catalytic component, and ammonia as a solvent. The method is characterised i n that a) adipodinitrile is hydrogenated at temperatures of 70 to 220 ~C and a t pressures of 100 to 400 bar in the presence of catalysts based on elementary iron as the catalytic component, and ammonia as a solvent to produce a mixtu re containing adipodinitrile, 6-aminocapronitrile, hexamethylene diamine and hi gh boilers, until the sum of the 6-aminocapronitrile and adipodinitrile concentration is 1 to 50 wt. % in relation to the ammonia-free hydrogenation mixture; b) ammonia is separated out of the hydrogenation discharge; c) hexamethylene diamine is separated out of the remaining mixture; d) 6- aminocapronitrile and adipodinitrile are separated from the high boilers together or separately and e) 6-aminocapronitrile, adipodinitrile or their mixtures are returned to step a).
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申请公布号 |
CA2342178(A1) |
申请公布日期 |
2000.03.09 |
申请号 |
CA19992342178 |
申请日期 |
1999.08.17 |
申请人 |
BASF AKTIENGESELLSCHAFT |
发明人 |
REHFINGER, ALWIN;FISCHER, ROLF;VOIT, GUIDO;MELDER, JOHANN-PETER;MERGER, MARTIN;ANSMANN, ANDREAS;BASSLER, PETER;OHLBACH, FRANK;LUYKEN, HERMANN |
分类号 |
C07B61/00;C07C209/48;C07C209/86;C07C211/12;(IPC1-7):C07C209/48 |
主分类号 |
C07B61/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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