| 摘要 |
PROBLEM TO BE SOLVED: To easily obtain a resin catalyst for activation of active hydrogen which has excellent catalytic function, high heat resistance and small deterioration by heating, by incorporating a resin having a cyclic amine structure into a resin catalyst for activation of active hydrogen in compds. containing active hydrogen and then forming the catalyst into granules. SOLUTION: The granular resin catalyst containing a resin having a cyclic amine structure shows excellent catalytic function for activation of active hydrogen in compds. containing active hydrogen, and suppresses dissolution of nitrogen atoms. To obtain the resin catalyst above described, the resin catalyst for activation of active hydrogen in compds. containing active hydrogen is produced by incorporating a resin having a cyclic amine structure and then formed into granules. Active hydrogen in compds. containing active hydrogen is activated in the presence of the resin catalyst above described. As for the compd. containing active hydrogen, carboxylic acids or their esters are used. Activation of active hydrogen is carried out by adding a cyclic heterocompd. to the carboxylic acids or their esters. |
