摘要 |
1.211,949. Oligomerisation catalysts. SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ N.V. 19 June, 1969 [21 June, 1968; 13 Jan., 1969 (2)], No. 31081/69. Heading B1E. [Also in Division C5] An oligomerisation catalyst comprises a sulphided cobalt or nickel compound on an Al 2 O 3 -containing support which may be treated with an alkyl aluminium halide or a trialkyl aluminium. Suitable Co and Ni compounds for preparing the catalysts are the halides, NiO, and cobalt acetylacetonate. A Co catalyst may contain up to 5%w sulphur and a Ni catalyst up to 20%w sulphur. |