发明名称 Sterically hindered 4-amino-piperidine with a low dimer content, its production and use
摘要 PCT No. PCT/EP97/02763 Sec. 371 Date Nov. 12, 1998 Sec. 102(e) Date Nov. 12, 1998 PCT Filed May 28, 1997 PCT Pub. No. WO97/46528 PCT Pub. Date Dec. 11, 1997The invention relates to a process for reducing the dimerization of piperidines of the formula I where R1 to R4 are C1- to C6-alkyl, R1 and R2 and/or R3 and R4 together are a CH2 chain having 2 to 5 carbon atoms, which comprises adding to the piperidine from 0.001 to 0.2% by weight of a reducing agent of the formula MXH4-mYm, where M is an alkali metal, NR4, where R are identical or different C1-C4-alkyl groups, or an equivalent of an alkaline earth metal or an equivalent of zinc, X is boron or aluminum, Y is H or CN and m is 0 or 1. The invention also relates to a mixture of piperidines of the formula I, from 0.001 to 0.2% by weight of a reducing agent and from 1 to 1000 ppm of dimers of the piperidines of the formula I, and to the preparation of hindered amine light stabilizers therefrom.
申请公布号 US6013803(A) 申请公布日期 2000.01.11
申请号 US19980180580 申请日期 1998.11.12
申请人 BASF AKTIENGESELLSCHAFT 发明人 JULIUS, MANFRED;RUST, HARALD;KRAUSE, ALFRED;SIEGEL, HARDO;SIEGEL, WOLFGANG;WITZEL, TOM
分类号 C07B63/04;C07D211/58;C07D211/72;C07D221/20;C08K5/3435;(IPC1-7):C07D211/58 主分类号 C07B63/04
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