发明名称 |
PROCESS TO CONTINUOUSLY PREPARE AN AQUEOUS MIXTURE OF (E)-CAPROLACTAM AND (E)-CAPROLACTAM PRECURSORS |
摘要 |
This continuous process for preparing an aqueous mixture of +531 -caprolactam and 6-aminocaproic acid and/or 6-aminocaproamide by involves, as the reductive amination step, continuously contacting 5-formylvaleric acid or an alkyl 5-formylvalerate in water as solvent with hydrogen and an excess of ammonia in the presence of a ruthenium on carrier, as a catalyst, wherein the carrier is at least one of titanium oxide or zirconium oxide. The aqueous mixture can be used to prepare +531 -caprolactam. |
申请公布号 |
EP0968185(A1) |
申请公布日期 |
2000.01.05 |
申请号 |
EP19980903292 |
申请日期 |
1998.02.10 |
申请人 |
DSM N.V.;E.I. DU PONT DE NEMOURS AND COMPANY |
发明人 |
HERKES, FRANK, EDWARD;PESTMAN, ROBERT;BOOGERS, JEROEN, ANTONIUS, FRANCISCUS |
分类号 |
B01J23/46;C07B61/00;C07C227/08;C07C229/08;C07C231/14;C07C237/06;C07D201/08 |
主分类号 |
B01J23/46 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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