发明名称 PRODUCTION OF (POLY)ALKYLENE GLYCOL MONOALKYL ETHER
摘要 PROBLEM TO BE SOLVED: To produce a (poly)alkylene glycol monoalkyl ether in high selectivity and yield advantageously on an industrial scale with little activity loss of a catalyst under suppression of alcohol by-production by reacting an olefin with a (poly)alkylene glycol under controlling the concentration of water in the reaction liquid below a specific level. SOLUTION: The reaction of (A) an olefin with (B) a (poly)alkylene glycol in the presence of (C) a catalyst (preferably, a crystalline metallosilicate) is carried out under controlling the concentration of water in the reaction liquid below 15 wt.% based on the total of the weights of the component B and water in the reaction liquid. Preferably, the component A is a 6-30C olefin, e.g. hexene, and a part or the whole part of unreacted component B is recycled as a raw material (poly)alkylene glycol.
申请公布号 JPH11349512(A) 申请公布日期 1999.12.21
申请号 JP19980155931 申请日期 1998.06.04
申请人 NIPPON SHOKUBAI CO LTD 发明人 KIRISHIKI MASARU;ONDA YOSHIYUKI;TSUNEKI HIDEAKI;SUMINO YUKIO
分类号 B01J29/70;C07B61/00;C07C41/06;C07C43/13 主分类号 B01J29/70
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