| 摘要 |
A di-p-tolyldialkylsilane derivative, a photoluminescence polymer formed from the derivative, and methods for preparing the derivative and polymer are provided. The di-p-tolyldialkylsilane derivative is represented by the following formula (1): where R1 and R2 are independently selected from the group consisting of phenyl and -(CH=CH)kR3 (k is an integer between and inclusive of 0 and 2, and R3 is hydrogen or alkyl), and X2 is selected from the group consisting of hydrogen, halogen atom and cyano group. The di-p-tolylalkylsilane derivative of the formula (1) is very useful as a monomer of a functional polymer. The photoluminescence polymer formed from the di-p-tolylalkylsilane derivative of the chemical formula (1) contains a repeating unit having a silicon between the conjugated double bonds, thereby suppressing electron movement of the conjugated double bond. As a result, a range of colors between blue and green, particularly, blue, can be obtained. Also, when the photoluminescence polymer is adopted as a color-developing substance, the threshold voltage characteristics are improved.
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