摘要 |
In order to lower the sulfuric content of the offgas from a smelter reactor in which iron oxide is reduced to molten iron, in the presence of sulfur contaminants, a sufficient amount of a source of zinc is included in the charge to the reactor that the combined weight of the zinc source and the iron oxide source contains at least about 0.6% Zn (calculated as elemental zinc), on a dry weight basis. The temperature of the offgas is maintained at or above approximately 700 DEG C. Vaporized zinc, present in the offgas, binds with sulfur in the offgas to precipitate solid ZnS. After removal of the ZnS, the offgas may have a sulfuric content below 50 ppm by volume of H2S equivalent. Suitable sources of zinc include blast furnace dust, electric arc dust, basic oxygen furnace dust, zinc calcine, and zinc sinter.
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