| 摘要 |
<p>Reactive dye compounds having formula (I), wherein D is a chromophore; X and Y are independently selected from SR', Cl, Br, or F, wherein R' is selected from: H, Cl-C4 alkyl, (CH2)nCOOH, (CH2)nCONH2, (CH2)nSO3H, (CH2)nCOOM, (CH2)nPO3H, (CH2)nOH, (CH2)nSSO3-, (CH2)nNR'2, (CH2)nN+R'3, PhSSO3-, PhSO¿3?H, PhPO3H, PhNR'2, PhN?+R'¿3, -CN, SO3-, (CH2)2CH(SH)R'(CH2)3COOH, -CH2CHOHCH2SH, and (1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12), -CH2CH2NH2. n is an integer in the range of 1 to 4 wherein within the same molecule n is not necessarily the same integer; and M is a cation of alkaline earth metal, alkali metal, NH4+ or NR'¿3?+. L is a linking moiety; Z is a nitrogen containing heterocycle selected from pyridone, quinoxaline or pyrimidone; provided that at least one of X or Y is SR' and esters and salts thereof. The reactive dye compounds of the present invention provide improved wash fastness of dye on hair and less colour fade over time.</p> |
