发明名称 LIQUID PHASE ETHYLENE OXIDATION CATALYST AND PRODUCTION OF ETHYLENE OXIDE IN LIQUID PHASE
摘要 PROBLEM TO BE SOLVED: To provide a catalyst for producing ethylene oxide in a liquid phase and the producing method and to produce ethylene oxide by oxidizing ethylene in the liquid phase. SOLUTION: The catalyst contains (1) a silver particle, (2) if necessary, one or more kinds of protective agents for the silver particle selected from a group composed of a hydrophilic high polymer, an amphipathic molecule and an anionic compound and (3) if necessary, one or more kinds of metallic compound selected from a group composed of an alkali metal, an alkaline earth metal and a rare earth metal. The average particle diameter of the silver particle is preferably <=50 nm and particularly, the silver particle is preferably silver colloid. The catalyst is brought into contact with a ethylene-containing gas to produce ethylene oxide from ethylene in the liquid phase. The producing method of ethylene oxide shows excellent safety and particularly suitable for producing a small quantity of ethylene oxide.
申请公布号 JPH11253802(A) 申请公布日期 1999.09.21
申请号 JP19980063557 申请日期 1998.03.13
申请人 NIPPON SHOKUBAI CO LTD 发明人 TOSHIMA NAOKI;SHIRAISHI YUKIE
分类号 C07D301/06;B01J13/00;B01J23/50;B01J23/66;C07B61/00;C07D303/04 主分类号 C07D301/06
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