发明名称 PRODUCTION OF ALKADIENOLS
摘要 PROBLEM TO BE SOLVED: To suppress the production of a high-boiling by-product, prevent the catalyst activity from deteriorating and produce the subject compound useful as a raw material, etc., for plasticizers by reacting a conjugated alkadiene with water in the presence of CO2 under specific conditions using palladium and an organophosphorus compound as the catalyst. SOLUTION: A conjugated alkadiene is reacted with water in the presence of CO2 using palladium and an organophosphorus compound as a catalyst to provide a reactional product solution containing alkadienols having a skeleton of the dimerized conjugated alkadiene. The molar ratio of the carboxylic acid to the palladium in the reaction product solution is 1-8 to carry out the reaction. After recovering the alkadienols from the reactional product solution, a liquid containing the remaining catalyst is reused for the reaction.
申请公布号 JPH11228469(A) 申请公布日期 1999.08.24
申请号 JP19980026969 申请日期 1998.02.09
申请人 MITSUBISHI CHEMICAL CORP 发明人 MORI TOMOYUKI;KAMEO HIROSHI;ISOTANI SHINJI
分类号 B01J31/24;C07B61/00;C07C29/44;C07C29/80;C07C33/035 主分类号 B01J31/24
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