| 摘要 |
PROBLEM TO BE SOLVED: To produce the subject compound useful for the dehydrohalogenation of organic compounds or synthesis, etc., of polymers in high yield without requiring the use of an acidic catalyst by reacting a specific lactone with a specified diamine while removing water of reaction during the progress of the reaction. SOLUTION: A lactone represented by formula I [R<a> and R<b> are each H or the like; (m) is 2-12] (e.g.γ-butyrolactone) is reacted with a diamine represented by formula II [R<x> and R<y> are each H or the like; (n) is 2-12] (e.g. 1,3-diaminopropane), preferably in at least 1:1.5 initial molar ratio of the lactone to the diamine, preferably continuously over the total reactional time, preferably at 170-220 deg.C for 5-100 hr while eliminating water of reaction and preferably with the aid of an azeotropic agent to produce the objective compound represented by formula III e.g. 1,5-diazabicyclo[4.3.0]non-5-ene}.
|
