发明名称 CATALYST FOR POLYMERIZATION OF ETHYLENE SYSTEM AND PRODUCTION OF ETHYLENIC POLYMER
摘要 PROBLEM TO BE SOLVED: To obtain the subject catalyst giving an ethylenic polymer, comprising a solid catalyst carrying a reaction product from a chromium compound with an organic metal compound, and a transition metal compound with an organic aluminum compound on a carrier, and having high molecular weight and large melt tension and suitable for an inflation film generating slight fish eye. SOLUTION: This catalyst is obtained by adding (B) a reaction product of a chromium compound (e.g. chromium carboxylate) with an organic metal compound (e.g. methyl lithium), (C) a solid catalyst carrying a reaction product of a transition metal compound e.g. bis(cyclopentadienyl)zirconium dichloride} including a group having a conjugateπ-electron as a ligand with an organic aluminum compound (e.g. aluminoxane), and preferably further (D) an organic metal compound, (E) a transition metal compound including a group having a conjugateπ-electron as a ligand on (A) a carrier (e.g. magnesia or titania).
申请公布号 JPH11228620(A) 申请公布日期 1999.08.24
申请号 JP19980034714 申请日期 1998.02.17
申请人 NIPPON POLYOLEFIN KK 发明人 TAKEMOTO YASUNORI;MONOI HISASHI;WAKI SHINYA;MORIMOTO TOSHIFUMI;INASAWA SHINTARO
分类号 C08F4/69;C08F4/639;C08F4/6392;C08F10/00;C08F10/02;(IPC1-7):C08F4/69 主分类号 C08F4/69
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