发明名称 PRODUCTION OF CINNAMIC ACID ESTERS
摘要 PROBLEM TO BE SOLVED: To inexpensively obtain a high-purity cinnamic acid ester useful as a synthetic intermediate for an antioxidant for plastics, an ultraviolet light absorber, a medicine, an agrochemical and a perfume industrially readily in a high yield. SOLUTION: A benzaldehyde is condensed with an acetic acid ester in the presence of a base, a reaction mixture is treated with an acid and a 3-alkoxy-3- phenylpropionic acid ester in the mixture is converted into a cinnamic ester of general formula III [X<1> to X<2> are the same or different and each hydrogen, a halogen, a 1-6C alkyl, alkoxy, haloalkyl, haloalkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino or a di(1-6C alkyl)amino group, nitro group, cyano group, phenyl group, phenoxy group or amino group and adjoining substituent groups of X<1> to X<2> may form a 5- to 6-membered saturated or unsaturated ring which may contain 1-4 oxygen, nitrogen or sulfur atoms].
申请公布号 JPH11217356(A) 申请公布日期 1999.08.10
申请号 JP19980293130 申请日期 1998.10.15
申请人 SANKYO CO LTD 发明人 OKUI HIDEFUMI;TSUKAMOTO YOSHIHISA;MIO SHIGERU
分类号 B01J31/02;C07B61/00;C07C67/327;C07C67/343;C07C69/618;C07C69/65;C07C69/734;C07C201/12;C07C205/56;C07C227/16;C07C229/44;C07C253/30;C07C255/57;C07C315/04;C07C317/44;C07C319/20;C07C323/62 主分类号 B01J31/02
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