发明名称 PR0DUCTION OF ORGANOSILICON COMPOUND HAVING SPECIFIC GAMMA-AMINOPROPYLSILYL GROUP
摘要 <p>PROBLEM TO BE SOLVED: To produce the subject compound in high yield by reacting an organoslicon compound having an alkylhydrosilyl group or an arylhydrosilyl group with an allylamine compound in the presence of a rhodium catalyst, a basic compound and a specific organosilicon compound. SOLUTION: (D) An organosilicon compound having an alkylhydrosilyl group or an arylhydrosilyl group (e.g. dimethylphenoxysilane) is reacted with (E) an allylamine compound (e.g. allylamine) in the presence of (A) a rhodium catalyst [e.g. bis(ethylene)rhodium (I) acetylacetonate], (B) a basic compound (e.g. tetraethylammonium hydroxide) and (C) an organosilicon compound represented by the formula, HSi(OR<1> )3 (R<1> is an alkyl or the like), preferably at 80 deg.C to produce the objective compound.</p>
申请公布号 JPH11209384(A) 申请公布日期 1999.08.03
申请号 JP19980006809 申请日期 1998.01.16
申请人 DOW CORNING ASIA KK 发明人 TACHIKAWA MAMORU
分类号 B01J23/46;C07B61/00;C07F7/10;C07F7/18;C08G77/26 主分类号 B01J23/46
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