发明名称 POLYMERIZATION CATALYST FOR COPOLYMER AND PRODUCTION OF COPOLYMER
摘要 PROBLEM TO BE SOLVED: To obtain the subject polymerization catalyst having high stability in high-temperature polymerization and reproducibility of the catalytic activity and more easily synthesizable for industrial use by combining a tetravalent group 4 metal complex with a metallic compound or a cation generation agent each having respectively specific structure. SOLUTION: This catalyst contains (A) a complex expressed by the formula [M is a group 4 transition metal; Y is C, Si or Ge; R<1> , R<2> , X<1> an X<2> are each a 1-12C alkyl, an alkoxy, an aryl or the like; Z<1> and Z<2> are each N, P or S; Ar<1> and Ar<2> are each an aryl, an aryloxy, silyl or the like; (m) is an integer of 1-5] and preferably further (B) an alkylaluminumoxy compound and/or (C) a cation generation agent. The catalyst preferably further contains an alkylaluminum compound, an alkyl-alkali metal compound or an alkyl-alkaline earth metal compound.
申请公布号 JPH11199624(A) 申请公布日期 1999.07.27
申请号 JP19980014762 申请日期 1998.01.12
申请人 ASAHI CHEM IND CO LTD 发明人 KAMO HIROSHI
分类号 C08F4/642;C08F4/646;C08F4/659;C08F4/6592;C08F210/02;(IPC1-7):C08F4/642 主分类号 C08F4/642
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