发明名称 |
Catalytic production of aryl alkyl hydroperoxides by polynuclear transition metal aggregates |
摘要 |
A method is provided for preparing organic hydroperoxides by oxidizing aryl alkyl hydrocarbons having a benzylic hydrogen with an oxygen containing gas using as a catalyst an oxo (hydroxo) bridged tetranuclear metal complex having a mixed metal core, one metal of the core being a divalent metal selected from Zn, Cu Fe, Co, Ni, Mn or mixtures thereof and another metal being a trivalent metal selected from In, Fe, Mn, Ga, and Al. A method is also provided for the manufacture of the catalyst
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申请公布号 |
US5922920(A) |
申请公布日期 |
1999.07.13 |
申请号 |
US19960626739 |
申请日期 |
1996.04.02 |
申请人 |
EXXON CHEMICAL PATENTS INC. |
发明人 |
BOND, JEFFREY EVANS;GORUN, SERGIU MIRCEA;SCHRIVER, GEORGE WILLIAM;STIBRANY, ROBERT TIMOTHY;VANDERSPURT, THOMAS HENRY;VIA, GRAYSON HALL;ZHANG, BAOSHAN;DAKKA, JIHAD MOHAMMED |
分类号 |
B01J31/04;B01J31/16;B01J31/18;B01J31/22;C07C39/04;C07C45/53;C07C409/08;C07C409/10;C07C409/14;(IPC1-7):C07C45/00;C07F13/00 |
主分类号 |
B01J31/04 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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