| 摘要 |
<p>Disclosed are silicone polymers comprising: a) formulae (Ia), wherein [A]m and [B]n, individually, is a non-reacting polymeric substituent wherein m + n is an integer of 1 to about 100,000, where one of m or n can be 0; and at least one of X?1, X2, and X3¿ is formulae (Ib): wherein Q1 is oxygen, nitrogen, sulfur or methylene; X is an integer of 0 to about 20; Y is an integer of 0 to about 20; Z is an integer of 0 to about 20; Q2 is CH¿2? or any of formulae (1, 2, 3 or 4); V is 0 or 1; R?1¿ is hydrogen, alkyl of 1 to 4 carbons, fluorocarbon of 1 to 4 carbons, phenyl, or benzyl; R2 is alkyl of 1 to about 30 carbons, phenyl, benzyl, or phenethyl; R3 is ethylene or propylene; Q3 is OH, OR8, NH2, NHR9, SH, SR10, COOH, COOR11, or a halogen, wherein R?8, R9, R10, and R11¿ are alkyl or alkylene of 1 to about 20 carbons; and W is an integer of 1 to about 100; the remainder of X?1, X2, and X3¿ being a non-reacting end group; and b) a stoichiometric amount of an anion selected from the group consisting of anionic forms of sulfate, hydrosulfate, methylsulfate, carbonate, bicarbonate, chloride, bromide, iodide, and mixtures thereof. Still further disclosed are suitable methods of making the silicone polymers.</p> |
