发明名称 CATALYST FOR OLEFIN POLYMERIZATION AND POLYMERIZATION OF OLEFIN USING THE CATALYST
摘要 PROBLEM TO BE SOLVED: To obtain a catalyst for olefin polymerization enabling continuous operation of a commercial plant without causing adhesion, etc., of a polymer to a reactor during polymerization by bringing a specific transition metal compound into contact with a specific active compound, a specific compound and a solid material, etc. SOLUTION: This catalyst is obtained by bringing (A) a transition metal compound having a cyclicηbinding anion ligand into contact with (B) an activated compound comprising a cation capable of forming a non-coordinating anion having compatibility with a cation capable of forming a metal complex having catalyst activity by reacting with the component A and used in an amount corresponding to 0.5-10 mol based on 1 mol component A, (C) an organometal oxy compound having an unit of the formula [M<2> is a metal of the group XIII to XV of periodic table or metalloid; R is a 1-12C hydrocarbon or a substituted hydrocarbon; (n) is a valence of a metal M<2> ; (m) is >=2], (D) a solid material and (E) a necessary, an organoaluminum compound. The catalyst is especially useful for ethylene polymerization.
申请公布号 JPH11166009(A) 申请公布日期 1999.06.22
申请号 JP19970343631 申请日期 1997.12.01
申请人 ASAHI CHEM IND CO LTD 发明人 MATSUSHITA FUMIO;IWASHITA YUKITOSHI
分类号 C08F4/642;C08F4/659;C08F4/6592;C08F10/00;C08F10/02;(IPC1-7):C08F4/642 主分类号 C08F4/642
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