发明名称 LONG-LIVED HOMOGENOUS OXIDATION CATALYSTS
摘要 <p>A robust chelate complex is provided having the formula: wherein: M is a metal, preferably a transition metal; Z is an anionic donor atom, three of which are nitrogen, and the other is oxygen; L1 is a labile ligand; Ch1, Ch2 and Ch3 are oxidation resistant chelate groups which are the same or different and which form 5 or 6 membered rings with the metal, and Ch4 is a chelate group having the structure wherein R1 and R2 are the same or different and are preferably selected from the group consisting of hydrogen, halogen, methyl, and CF3 or when linked, a five or six membered ring cyclo substituent. The complex provides a stable, long-lived oxidation catalyst or catalyst activator.</p>
申请公布号 EP0914206(A1) 申请公布日期 1999.05.12
申请号 EP19970938014 申请日期 1997.07.21
申请人 CARNEGIE MELLON UNIVERSITY 发明人 COLLINS, TERRENCE, J.;GORDON-WYLIE, SCOTT, W.
分类号 B01J31/22;B01J31/18;C07D257/02;C07D257/10;C07F15/00;(IPC1-7):B01J31/18 主分类号 B01J31/22
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