| 摘要 |
<p>A method of forming high impact copolymer having a high degree of crystallinity and a melt flow rate of at least 10 to 150. The method preferably comprising: subjecting the α-olefin monomer to an initial polymerization, in the presence of a first electron donor material and a first catalyst to form a polymer product; subjecting the polymer product to a subsequent polymerization, in the presence of a second electron donor material and a second catalyst, thereby forming the α-olefin homopolymer; wherein the second donor material is more stereoregulating than the first electron donor material and the second electron donor material dominates the first electron donor material; and polymerizing a copolymer in the presence of the α-olefin homopolymer; thereby forming a high impact copolymer. The first and second catalysts may be the same or different. The copolymer portion of the high impact copolymer will have an unexpected high amorphous phase content.</p> |
