发明名称 |
PRODUCTION OF ALDEHYDE AND KETONE OR ITS DERIVATIVE, PRODUCTION OF X-RAY AMORPHOUS ZINC SILICATE OR CADMIUM SILICATE AND X-RAY AMORPHOUS ZINC SILICATE CATALYST OR CADMIUM SILICATE CATALYST |
摘要 |
PROBLEM TO BE SOLVED: To obtain the subject compound at a low temperature, by adding a hydroxyl group-containing compound to an alkyne, etc., in the presence of an amorphous zinc silicate catalyst, etc. SOLUTION: A compound of the formula R<1> OH (R<1> is H, an aliphatic or alicyclic group) is added to an acetylene or allene of formula I or formula II (R is H, an aliphatic or alicyclic group) in a gas phase by using a catalyst containing 1-40 wt.% calculated as oxide of zinc or cadmium-containing X-ray amorphous zinc silicate or cadmium silicate as an active ingredient and obtained by setting a zinc salt or a cadmium salt of an acidic organic compound decomposable at a temperature lower than 400 deg.C on amorphous silicic acid and forming the catalyst at 50-500 deg.C in the presence of hydrogen and a hydroxyl group-containing compound such as a <=10C alkanol or a 2-6C diol containing 2-3 hydroxyl groups to give the objective compound of formula III or formula IV ((m) is 0 or 1). |
申请公布号 |
JPH1171313(A) |
申请公布日期 |
1999.03.16 |
申请号 |
JP19980175055 |
申请日期 |
1998.06.22 |
申请人 |
BASF AG |
发明人 |
TELES JOAQUIM HENRIQUE DR;RIEBER NORBERT DR;BREUER KLAUS DR;RIEKER CHRISTOPHER WILLIAM DR;DEMUTH DIRK DR;HIBST HARTMUT;HAGEMEYER ALFRED DR |
分类号 |
B01J23/06;B01J37/02;C07B61/00;C07C41/06;C07C41/08;C07C41/54;C07C43/15;C07C43/303;C07C67/04;C07C69/145;C07C69/16;(IPC1-7):C07C43/15 |
主分类号 |
B01J23/06 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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