发明名称 PRODUCTION OF POLYHYDRIC ALCOHOL ADDUCT OF ALICYCLIC HYDROCARBON AND CATALYST USING IN THE PRODUCTION
摘要 PROBLEM TO BE SOLVED: To produce the subject compound useful as a modifier, etc., of a polyester resin, an alkyd resin or the like in high selectivity and high yield by reacting an alicyclic hydrocarbon with a polyhydric alcohol in the presence of a specific catalyst. SOLUTION: This compound is obtained by reacting an alicyclic hydrocarbon having at least one double bond (preferably dicyclopentadiene) with a polyhydric alcohol (e.g. ethylene glycol) in the presence of a catalyst containing crystalline metallosilicate, and using a solvent (e.g. nitromethane), as necessary, preferably under normal pressure -20 kg/cm<2> at 80-160 deg.C for 1-8 hrs. A compound suitable as the crystalline metallosilicate, a compound in which whole or a part of cation is substituted with a hydrogen ion, a BEA-type compound or a pentasil- type compound. preferably, a using amount of the catalyst is 0.5-50 wt.% and a mol ratio of the polyhydric alcohol is 1-10, respectively to the alicyclic hydrocarbon.
申请公布号 JPH1160531(A) 申请公布日期 1999.03.02
申请号 JP19970223402 申请日期 1997.08.20
申请人 NIPPON SHOKUBAI CO LTD 发明人 MORIYA ATSUSHI;ONDA YOSHIYUKI;TSUNEKI HIDEAKI
分类号 B01J29/40;C07B61/00;C07C41/06;C07C43/196 主分类号 B01J29/40
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