发明名称 |
Process for the preparation of p-bromotoluene |
摘要 |
A crude bromotoluene mixture comprising at least 70 wt % of a mixture of p-bromotoluene and o-bromotoluene, and wherein the weight ratio of p-bromotoluene:o-bromotoluene is in the range of 50:50 to 99:1 is cooled to a temperature at which crystals of product enriched in p-bromotoluene are formed in a first residual mother liquor. After removing the residual mother liquor from the crystals of product enriched in p-bromotoluene, the crystals are partially melted to form a mixture of residual higher purity p-bromotoluene in the form of crystals, and a second mother liquor having a higher content of o-bromotoluene than said first residual mother liquor. This higher purity p-bromotoluene and the second mother liquor are separated from each other. The entire procedure starting with the above cooling step can be repeated as a second stage and again as a third stage each time using as the initial feed the residual higher purity p-bromotoluene that is separated from the second mother liquor of the preceding stage. Product of 99.5 wt % purity can be formed in this manner.
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申请公布号 |
US5874659(A) |
申请公布日期 |
1999.02.23 |
申请号 |
US19980078380 |
申请日期 |
1998.05.13 |
申请人 |
ALBEMARLE CORPORATION |
发明人 |
LUSSON, CHRISTOPHE-HENRI PIERRE |
分类号 |
C07C17/392;C07C25/02;(IPC1-7):C07C22/00 |
主分类号 |
C07C17/392 |
代理机构 |
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