POLYMERIZABLE ADAMANTANE DERIVATIVE AND ITS PRODUCTION

摘要

PROBLEM TO BE SOLVED: To obtain the subject compound in high yield restrained from immixing a halogenous compound therein by subjecting a specific adamantane derivative and compound with a polymerizable unsaturated bond to esterification reaction or amidation reaction in the presence of a catalyst formed of a compound of a group III element in the periodic table. SOLUTION: This objective compound shown by formula II (R<1> to R<4> are each a polymerizable unsaturated group; X is a combination group; and (n) is 0 or 1) is obtained by subjecting an adamantane derivative shown by formula I (R<1a> to R<4a> are each an amino group, etc.) and compound (e.g. aryl chloride) selected from the group consisting of an alcohol (e.g. aryl alcohol) with a polymerizable unsaturated bond, carboxylic acid (e.g. fumaric acid), amine (e.g. aryl amine), and the reactive derivative thereof to esterification reaction or amidation reaction in the presence of a catalyst (e.g. halide of samarium) formed of a compound of a group III element in the periodic table.