| 摘要 |
NEW MATERIAL:A compound expressed by the formula {R<1> to R<8> represent H or F and at least one is F; Z consists of n-valent cation [M<n+>(n is 1-5)] of an element in I A-VI A, I B-VII B and VIII groups, O and anion (X<->) of F<->, Cl<->, Br<->, I<->, O<->, OH<->, CH3O<->, C6H5O<->, SCN<->, etc., and takes the form of any one of 2M<+>, H<+>M<+>, M<2+>, M<3+>X<->, M<4+>X, O=M<4+> and O=M<5+>X<->}. EXAMPLE:2,3,7,8,12,13,17,18-Octafluoro-5,10,15,20-tetrakis(pentafluoro phenyl) porphyrinato.zinc. USE:An oxidizing catalyst for organic compound. PREPARATION:For example, 5,10,15,20-tetrakis(pentafluorophenyl)-21H,23H- porphyrin is dissolved in a solvent, mixed with a methanol solution of zinc acetic anhydride and heated while being stirred to afford 5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato.zinc. |
