Complexes containing tris-(hydroxyalkyl)-phosphines as ligands for telomerizations, as catalysts and new complexes containing tris-(hydroxyalkyl)-phosphines

摘要

In a process for the telomerization of dienes with nucleophiles in a liquid two-phase system, use is made as catalysts of complexes comprising a transition metal as central atom and at least one tris-(hydroxyalkyl)-phosphine or -phosphine oxide as ligand. The use as catalysts of compounds comprising a transition metal as central atom and at least one tris-(hydroxy-C2-C5-alkyl)-phosphine or -phosphine oxide as ligand, new compounds of this type and aqueous solutions of such compounds are likewise described.