发明名称 |
Metal silicate compositions and catalysts |
摘要 |
A high silica zeolite (UTD-1) using bis(pentamethyl-cyclopentadienyl)cobalt(III) hydroxide, Cp*2CoOH is disclosed. UTD-1 is a large pore molecular sieve having one dimensional channels running in parallel. The synthesis and characterization of silicates incorporating titanium, vanadium, aluminum or boron in the silicate framework is described. Calcined Ti-UTD-1 containing cobalt oxide and the cobalt free molecular sieves are shown to be effective oxidation catalysts. Oxidation of alkanes with hydrogen peroxide and t-butylhydroperoxide (t-BHP) and the room temperature oxidation of cyclohexane to adipic acid are demonstrated.
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申请公布号 |
US5830429(A) |
申请公布日期 |
1998.11.03 |
申请号 |
US19960599536 |
申请日期 |
1996.02.06 |
申请人 |
BOARD OF REGENTS, THE UNIVERSITY OF TEXAS SYSTEM |
发明人 |
BALKUS, JR., KENNETH J.;GABRIELOV, ALEXEI G. |
分类号 |
B01J29/035;B01J29/04;B01J29/86;B01J29/89;C01B37/00;C07C29/48;C07C51/285;(IPC1-7):C01B39/04;B01J29/06 |
主分类号 |
B01J29/035 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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