Einstufiges Verfahren zur Herstellung von alpha-Hydroxyethern durch Oxidation C=C-ungesättigter Verbindungen mit Hydroperoxiden

摘要

The invention relates to a single-stage method for producing alpha -hydroxy ethers corresponding to formulae (I) and (II), by oxidizing olefinic substrates with organic hydroperoxides and opening the resulting oxirane ring by means of monovalent or polyvalent alcohols. Molybdenum compounds in combination with boron trifluoride or aluminum oxide or 1.8-diazabicyclo-[5.4.0]-undec-7-ene or 1.4-diazabicyclo-[2.2.2]-octane can be used as a catalyst system.