| 摘要 |
An elastomer prepared from a composition containing an amount of unconjugated diene not substantially higher than 1 mole of diene per kilogram of composition is compounded with sulphur or an organic disulphide and one or more organic peroxides of formula <FORM:1099995/C3/1> wherein some or all of the hydrogen atoms of the cyclohexyl nucleus may be substituted by similar or dissimilar alkyl, cycloalkyl or alkylcycloalkyl groups having 1 to 9 carbon atoms in a quantity sufficient for cross-linking. Elastomers specified are polyethylene, ethylene-propylene and ethylene-vinyl acetate copolymers and ethylene-propylene terpolymers. The organic disulphide may be tetramethyl or tetraethyl thiuram disulphide, an alkyl phenol disulphide or morpholine disulphide. Auxiliary agents, e.g. diphenyl guanidine, ZnO, MgO, antioxidants, an allyl ester of a dibasic or polybasic acid, an aromatic or aliphatic compound having at least two vinyl groups, or an acrylate of a dihydric or polyhydric alcohol may also be included in the composition as can fillers and carriers for the peroxide catalysts. In the examples, the compositions comprise carbon black and (1) ethylene-propylene copolymer, sulphur, 1,1 - bis -(30 - butyl peroxy) - 3,3, 5-trimethylcyclohexane, and calcium silicate, (2) ethylene-propylene copolymer, sulphur, 2-cyclohexyl - 2 - (4,4 -di - tert - butyl peroxycyclohexyl)-propane and, optionally, CaCO3 or calcium silicate, (3) ethylene-vinyl acetate copolymer, tetramethyl thiuramdisulphide, 1,1-bis-(30-butylperoxy)-3,3,5-trimethylcyclohexane, and calcium silicate, (4) ethylenepropylene copolymer, sulphur, calcium silicate and a catalyst selected from 1,1-bis-(30-butylperoxy)-3, 3,5 - trimethylcyclohexane, 1,1-bis-(30-butylperoxy) - cyclohexane, 1,1-bis-(30-butylperoxy)-2,5-dimethylcyclohexane and 1,1-bis-(30-butylperoxy)-3,4-dimethylcyclohexane, (5) ethylene-propylene-diene terpolymer, sulphur, 1,1-bis-(30-butylperoxy)-3,3,5-trimethylcyclohexane and calcium silicate and (6) polyethylene, sulphur, 1,1-bis-(30-butylperoxy)-3,3,5-trimethylcyclohexane, and filler. The compositions are compounded at below 120 DEG C. and cross-linked at 140 DEG to 165 DEG C. |
