Method for processing chromium oxide-containing substances in large quantities

摘要

A method of rapidly reducing chromium oxide-containing slag and the like in large quantities, in a simplified manner and without requiring high temperatures. Chromium oxides are reduced with at least one of elementary sulfur and compounds of sulfur having a valence less than 6. For an aqueous solution of the sulfur component, desirably, its sulfur content is more than 0.03 % by weight. As the sulfur source, preferred is blast furnace slag (e.g., non-aged, gradually-cooled blast furnace slag) that is discharged in large quantities in the iron industry. Cr<6+> in chromium oxides is reduced in one of the following ways: (a) Chromium oxide-containing substances are sprayed with or immersed in blast furnace slag-released water that has been used in cooling blast furnace slag. (b) Chromium oxide-containing substances are mixed with blast furnace slag, and then kept in an air atmosphere. Optionally, the mixture is sprayed with blast furnace slag-released water. (c) Chromium oxide-containing substances are mixed with blast furnace slag, and then steamed. (d) Prior to the reduction treatment, chromium oxide-containing substances are preferably steamed. 100 parts by weight of reduced chromium oxide-containing compounds are mixed with from 0.1 to 90 parts by weight of sulfur-containing slag, and used in various civil engineering works.