| 摘要 |
A supported alpha-olefin polymerization catalyst composition of this invention is prepared in a multi-step process. The process for catalyst production comprises (i) providing a slurry in a non-polar solvent of a solid porous inorganic support having reactive hydroxyl groups; (ii) impregnating said support having hydroxyl groups, with RMgR min compound, to form a white intermediate, which intermediate has a Mg:hydroxyl group ratio of greater than 1, wherein each of said R and R min is alkyl of 1 to 12 carbon atoms and is the same or different; (iii) treating the intermediate of step (ii) with a halogen containing reagent to form a brown intermediate of step (iii); (iv) treating the intermediate of step (iii) with TiCl4 to form a titanium containing intermediate which has a Ti/Mg ratio of greater than 0.5; (v) combining the titanium containing intermediate with a trialkylaluminum compound or a dialkyl aluminum hydride compound,wherein said halogen containing reagent is effective to increase the activity of a catalyst consisting of said support, said RMgR min , said TiCl4 and said alkylaluminum compound. The catalyst also produces polymers and copolymers having relatively an intermediate molecular weight distribution and improved flow index response. |
