Process for the preparation of acrolein from propyle by reaction

摘要

The use of a solid composition of mixed oxides of formula Mo12WaBibFecCodNieSifKgSnhOx (I), where a = 0-5; b = 0.5-5; c = 0.1-10; d = 0.5-10; e = 0-10; f = 0-15; g = 0-1; h = 0-2; and x = the quantity of oxygen attached to the other elements dependent on their oxidation states, in the manufacture of acrolein by oxidation of propylene is new. The solid composition reacts according to the following redox reaction SOLIDoxidised + Propylene -> SOLIDreduced + Acrolein (1).