发明名称 Selective chemical etching in microelectronics fabrication
摘要 The present invention relates to a chemical etchant for etching metals in the presence of one or more metals not to be etched, the etchant comprising 10-25 gms EDTA, 15-35 gms K2HPO4 and 25-45 gms oxalic acid in a liter of 30% H2O2. More particularly, in the fabrication of interconnections for microchip structures, the present invention addresses the removal of intermediate adherent layers, e.g., Ti-W, without damaging other microchip structures made of other metals, such as Al or Al-Cu test pads; Cu and phased Cr-Cu layers; and Sn-Pb solder bumps. The use of potassium phosphate in the hydrogen peroxide+EDTA bath has been found to significantly reduce the attack on the metal not to be etched. Furthermore, the use of oxalic acid in the bath prevented the deposition of tin oxide on the substrate adherent layer metal, thus facilitating its complete removal.
申请公布号 US5800726(A) 申请公布日期 1998.09.01
申请号 US19950507098 申请日期 1995.07.26
申请人 INTERNATIONAL BUSINESS MACHINES CORPORATION 发明人 COTTE, JOHN MICHAEL;DATTA, MADHAV;DINAN, THOMAS EDWARD;SHENOY, RAVINDRA VAMAN
分类号 C23F1/30;H01L21/3213;(IPC1-7):C23G1/14 主分类号 C23F1/30
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