发明名称 Resolution of racemates of 2-aryl-2-alkyl- omega -alkylaminoalkane-nitriles
摘要 PCT No. PCT/EP96/00236 Sec. 371 Date Jul. 7, 1997 Sec. 102(e) Date Jul. 7, 1997 PCT Filed Jan. 20, 1996 PCT Pub. No. WO96/23764 PCT Pub. Date Aug. 8, 1996A process for resolving the racemates of phenylacetonitriles of the formula I <IMAGE> I where R1, R2, R3 and m have the meanings stated in the description is described. The process comprises dissolving the racemates I in a polar solvent, adding from 0.5 to 1.0 mol of optically active camphorsulfonic acid per mol of compound I, heating to 40 DEG -100 DEG C., allowing to cool and liberating the optically active phenylacetonitrile I from the salt obtained in this way.
申请公布号 US5786498(A) 申请公布日期 1998.07.28
申请号 US19970860664 申请日期 1997.07.07
申请人 BASF AKTIENGESELLSCHAFT 发明人 KARL, ULRICH;SEITZ, WERNER
分类号 C07B57/00;C07C253/34;C07C255/43;(IPC1-7):C07C253/00 主分类号 C07B57/00
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