发明名称 METHOD OF PREPARING DIFLUOROMETHANE
摘要 FIELD: chemical industry. SUBSTANCE: claimed method comprises contacting dichloromethane hydrogen fluoride in the presence of fluorination catalyst containing zinc or zinc compound, and metal oxide, fluoride or oxyfluoride. Temperature is preferably 240-320 C. HF to difluoromethane molar ratio varies from 5:1 to about 25:1, zinc content per catalyst weight 0.1-30 wt %, use of catalyst makes it possible to use lower temperatures than those generally used in the hydrofluorination of dichloromethane, whereas HCPC content does not increase. EFFECT: more efficient preparation method. 5 cl, 3 tblo
申请公布号 RU2116288(C1) 申请公布日期 1998.07.27
申请号 RU19950118158 申请日期 1994.03.14
申请人 IMPERIAL KEMIKAL INDASTRIZ PLS 发明人 DZHON DEHVID SKOTT;MAJKL DZHON UOTSON;DEHVID UILL'JAM BONNIFEJS
分类号 B01J21/04;B01J23/06;B01J23/20;B01J23/62;B01J23/70;B01J27/12;C07B61/00;C07C17/20;C07C19/08;(IPC1-7):C07C19/08 主分类号 B01J21/04
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