发明名称 |
Regeneration of severely deactivated reforming catalysts |
摘要 |
The invention is directed a process for regenerating deactivated reforming catalysts comprising at least one Group VIII metal on zeolite L, preferably wherein the catalysts are extruded using a binder material such as alumina or silica. The process includes: a) coke burn at severe conditions to improve the accessibility of the Group VIII catalytic metal particles by transporting them to the outside of the zeolite microchannels; b) catalytic metal redispersion by wet oxychlorination with elemental chlorine and oxygen; c) stripping with a gas stream comprising oxygen and water at low pressure to remove as much residual chlorine as possible; and d) reduction of catalytic metals with hydrogen at low pressure. The process is particularly effective for recovering activity of catalysts which have been severely deactivated.
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申请公布号 |
US5776849(A) |
申请公布日期 |
1998.07.07 |
申请号 |
US19920942694 |
申请日期 |
1992.09.09 |
申请人 |
EXXON RESEARCH & ENGINEERING COMPANY |
发明人 |
FUNG, SHUN CHONG;HUANG, YAO-JYH ROBERT;WALSH, JOHN FRANCIS;MCVICKER, GARY BRICE;CLEM, KENNETH RAY |
分类号 |
B01J29/62;B01J29/90;B01J38/44;C07B61/00;C07C5/387;C07C5/41;C07C15/04;C10G35/095;(IPC1-7):B01J29/90;B01J38/42 |
主分类号 |
B01J29/62 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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